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Creators/Authors contains: "Angeles-Boza, A. M."

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[Ru II (tpy)(bpy)Cl] + -Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects

https://doi.org/10.1039/C8CC03009J

Schneider, T. W. ; Hren, M. T. ; Ertem, M. Z. ; Angeles-Boza, A. M. ( January 2018 , Chemical Communications)

In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretical calculations methodology for probing CO 2 conversion reactions.
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